自然科学版 英文版
自然科学版 英文版
自然科学版 英文版
自然科学版 英文版
英文版编委
自然科学版 英文版
英文版首届青年编委

您目前所在的位置:首页 - 期刊简介 - 详细页面

中南大学学报(英文版)

Journal of Central South University

Vol. 22    No. 7    July 2015

[PDF Download]    [Flash Online]

    

Preparation of spiro-type quaternary ammonium salt via economical and efficient synthetic route as electrolyte for electric double-layer capacitor
ZHOU Hong-ming(周宏明)1, 2, SUN Wen-jiao(孙文佼)1, LI Jian(李荐)1, 2

1. School of Materials Science and Engineering, Central South University, Changsha 410083, China;
2. Hunan Zhengyuan Institute for Energy Storage Materials and Devices, Changsha 410083, China

Abstract:A spiro-type quaternary ammonium salt, spiro-(1,1′)-bipyrrolidinium tetrafluoroborate (SBP-BF4) was successfully prepared by an economical and efficient three-step process comprising the cyclization reaction of 1,4-dibromobutane and pyrrolidine, and subsequent ion exchange pathway with KOH followed by neutralization reaction via HBF4 in the system of ethanol solution. 1H NMR, 13C NMR, FI-IR and XPS analyses showed the structure of SBP-BF4. The as-obtained SBP-BF4 was dissolved in AN and used as the electrolyte for supercapacitor. Electrochemical measurements demonstrate that, compared with commercial electrolyte TEMA-BF4/AN, SBP-BF4/AN exhibits high ionic conductivity, lower resistance and improved cycling performance, which is due to its smaller ion size and stable symmetry structure.

 

Key words: spiro-type quaternary ammonium salt; synthesis; electrolyte; electric double-layer capacitor

中南大学学报(自然科学版)
  ISSN 1672-7207
CN 43-1426/N
ZDXZAC
中南大学学报(英文版)
  ISSN 2095-2899
CN 43-1516/TB
JCSTFT
版权所有:《中南大学学报(自然科学版、英文版)》编辑部
地 址:湖南省长沙市中南大学 邮编: 410083
电 话: 0731-88879765(中) 88836963(英) 传真: 0731-88877727
电子邮箱:zngdxb@csu.edu.cn 湘ICP备09001153号